Viscosity measurements in a solution undergoing inverse melting
نویسندگان
چکیده
منابع مشابه
Phase diagram of a solution undergoing inverse melting.
The phase diagram of alpha -cyclodextrin/water/4-methylpyridine solutions, a system undergoing inverse melting, has been studied by differential scanning calorimetry, rheological methods, and x-ray diffraction. Two different fluid phases separated by a solid region have been observed in the high alpha -cyclodextrin concentration range (c > or =150 mg/ml) . Decreasing c , the temperature interva...
متن کاملInverse melting and inverse freezing: a spin model.
Systems of highly degenerate ordered or frozen state may exhibit inverse melting (reversible crystallization upon heating) or inverse freezing (reversible glass transition upon heating). This phenomenon is reviewed, and a list of experimental demonstrations and theoretical models is presented. A simple spin model for inverse melting is introduced and solved analytically for infinite range, cons...
متن کاملConductivity and Viscosity Measurements for Binary Lysozyme Chloride Aqueous Solution and Ternary Lysozyme-Salt-Water Solution
We use the conductimetric method, adequate to electrolytes, to determine the lysozyme charge in lys-water and ternary lys-salt-water systems. We measured also the viscosities for the above binary and ternary systems in the same conditions at pH= 4.5 and T= 298 K, measurements that allow us to see any effect of viscosity on cations mobilities and implicitly on the lysozyme charge. The method is ...
متن کاملInverse melting in lattice-gas models.
Inverse melting is the phenomenon, observed in both helium isotopes, by which a crystal melts when cooled at constant pressure. I investigate discrete-space analogs of inverse melting by means of two instances of a triangular-lattice-gas system endowed with a soft-core repulsion and a short-ranged attraction. To reconstruct the phase diagram, I use both transfer-matrix and Monte Carlo methods, ...
متن کاملViscosity and Density Measurements
2. Working Equations of the Vibrating-Wire Instrument Our implementation [1] of the steady-state vibrating-wire technique is similar to that described by Audonnet and Pádua [2] in which the wire is driven at frequency f by a constant sinusoidal current I, and the emf V(f) generated across the vibrating wire is measured with a two-phase lock-in amplifier. This measured emf generally comprises tw...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Philosophical Magazine
سال: 2007
ISSN: 1478-6435,1478-6443
DOI: 10.1080/14786430600920839